Petroleum Science >2019,??Issue 1:??173-179 DOI: https://doi.org/10.1007/s12182-018-0285-3
Degradation of benzothiophene in diesel oil by LaZnAl layered double hydroxide: photocatalytic performance and mechanism Open?Access
文章信息
作者：Li-Guo Gao, Huan-Xiang Li, Xiao-Li Song, Wan-Lu Li and Xiang-Rong Ma
作者单位：
School of Chemistry and Chemical Engineering, Yulin University, Yulin, Shaanxi 719000, China,School of Chemistry and Chemical Engineering, Yulin University, Yulin, Shaanxi 719000, China,School of Chemistry and Chemical Engineering, Yulin University, Yulin, Shaanxi 719000, China,Department of Chemistry, Tsinghua University, Beijing 100084, China and School of Chemistry and Chemical Engineering, Yulin University, Yulin, Shaanxi 719000, China
投稿时间：2018-03-01
引用方式：Gao, LG., Li, HX., Song, XL. et al. Pet. Sci. (2019) 16: 173. https://doi.org/10.1007/s12182-018-0285-3
文章摘要
A new type of photocatalytic La3+–Zn2+–Al3+–MoO42- layered double hydroxide (LDH) material (molar ratio, La/Zn/ Al = 1:7:2) was prepared by a complexing agent-assisted homogeneous precipitation technique. The structure of the prepared LDH material was systematically studied. Under UV irradiation, the desulfurization efficiency of the LDH material was 87% in 2 h. For La3+–Zn2+–Al3+–MoO42- LDH material, the introduction of MoO42- increased the interlayer space for promoting the adsorption of benzothiophene (BT), and MoO42- might provide active sites for the oxidation of BT, resulting in the high desulfurization efficiency.
关键词
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LDH, Homogeneous precipitation, Photocatalytic activities, Catalytic oxidation mechanism